 | Ramirez Hidalgo - Klaassen 3:6 5:7 | 4 s |
| Devvarman - Bogdanovic 6:2 6:7(3) 6:4 | 3 s |
| Ljubičič - Troicki 4:6 7:5 4:6 | 3 s |
| Wawrinka - Sidorenko 6:4 6:4 | 2 s |
| Roddick - Soderling 6:7(5) 6:7(5) | 4 s |
| Lacko - Bachinger 6:1 6:7 6:1 | 6 s |
| Hanescu - Sidorenko 7:6(2) 6:4 | 3 s |
| Starace - M.Gonzalez 5:7 6:4 6:3 | 6 s |
| Luczak - Ascione 4:6 6:2 6:4 | 5 s |
| Bemelmans - Bracciali 6:4 6:4 | 7 s |
| Sharapova - Mchale 6:2 6:1 | 2 s |
| Goerges - Dentoni 7:5 6:4 | 3 s |
| Canas - Cuevas 2:6 6:3 6:7(2) | 1 s |
| Cibulkova - Shaughnessy 6:2 6:2 | 4 s |
| Krajicek - Rezai 3:6 0:6 | 2 s |
| Wozniacki - Ruano P. 6:3 6:3 | 2 s |
| Granollers - Di Mauro 6:2 6:4 | 5 s |
| Nadal - A.Murray 6:1 6:2 | 7 s |
| M.Gonzalez - Koellerer 3:6 3:6 | 4 s |
| Wozniacki - S.Peer 6:3 6:2 | 2 s |
 | R.Machado - Dabul 6:1 6:4 | 4 s |
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