 | S.Williams - M.J.martinez 4:6 6:3 6:4 | 7 s |
| Hocevar - Felder 6:2 6:4 | 3 s |
| Soderling - Vinciguerra 6:1 7:6(6) | 2 s |
| Zib - Balazs A. 6:3 3:6 5:7 | 3 s |
| Kindlmann - Snobel 6:4 6:1 | 6 s |
| Amanmuradova - M.J.martinez 2:6 4:6 | 4 s |
| M.Ancic - Schuttler 7:5 6:2 | 3 s |
| P.Santos - Flock 3:6 4:6 | 5 s |
| Tetreault - Sa.Jones 2:6 7:6(5) 7:5 | 3 s |
| Mattek - Keothavong 2:6 6:7(4) | 4 s |
| Dent - Dabul 7:5 6:2 | 3 s |
| Bellucci - P.Santos 6:7(6) 6:7(6) | 7 s |
| Zeballos - Bonatto 7:6(1) 2:6 7:5 | 6 s |
| Cibulkova - Gallovits 6:2 6:2 | 3 s |
| Zeballos - Pless 6:6 ret. | 2 s |
| Wawrinka - Petzschner 7:6(5) 2:6 6:7(5) | 7 s |
| Gasquet - Junqueira 6:7(5) 7:6(3) 6:3 6:4 | 5 s |
| Fognini - Villagran 4:6 6:2 6:2 | 3 s |
| B.Evans - F.Nielsen 1:6 2:6 | 4 s |
| Goerges - Dentoni 7:5 6:4 | 3 s |
| Alund - Ouahabi 3:6 3:6 | 7 s |
| Lisnard - Chaki 4:6 5:7 | 4 s |
| Robredo - Benneteau 2:6 2:6 | 6 s |
| Tipsarevic - Roitman 7:5 6:2 | 4 s |
| Safina - Jankovic 4:6 2:6 | 6 s |
| Recouderc - R.Ghedin 6:2 4:6 6:1 | 4 s |
| Chakvetadze - Vesnina 7:5 6:3 | 8 s |
| Voskoboeva - Beygelzimer 2:6 6:7(5) | 8 s |
| Kunitsyn - Hernych 6:4 7:6(5) | 8 s |
| Moraru - Brizzi 6:4 5:7 3:6 | 5 s |
| S.Ventura - Ouahab 6:4 2:6 2:6 | 8 s |
| D.Young - Im 6:4 4:3 ret. | 6 s |
| Ondraskova - Mladenovic 7:6(0) 6:2 | 5 s |
| Devvarman - L.Cook 6:7(5) 5:7 | 8 s |
| Dubois - S.Zhang 6:4 4:6 4:6 | 7 s |
| M.Gonzalez - Berlocq 6:4 4:6 4:3 ret. | 4 s |
| S.Williams - S.Peng 6:1 6:4 | 5 s |
| Ball - Van Der merwe 6:4 6:3 | 7 s |
 | F.Mayer - Sidorenko 6:4 6:3 | 9 s |
Trenéři
Head Liquidmetal (Agassi) | 
